Black smoke has issued from the Sistine Chapel in Rome, signalling that the second and third votes in the Papal election have been inconclusive.
Cardinals have been meeting for a second day to choose a successor to Pope Benedict, who resigned last month.
The 115 electors are shut off in the Sistine Chapel and a nearby residence until two-thirds agree on a leader for the world's 1.2 billion Catholics.
Further votes will be held on Wednesday afternoon.
At the scene
Michael Hirst BBC News, Rome
A panorama of multi-coloured umbrellas massed on St Peter's Square on Wednesday morning as pilgrims braved tempestuous conditions to take up their smoke-watch vigil.
The faithful huddled in their plastic ponchos - it's been a bumper time for street-hawkers selling plastic sheets and cheap brollies.
Eyes darted between the rust-coloured chimney stack on the Sistine Chapel and the big screens dotted around the square.
Some carrying bedraggled national flags were backing their country's favourites. Some were praying for peace and unity in the Church.
Other still just wanted the cardinals would clear out of the Sistine Chapel so they could get a glimpse of Michelangelo's Last Judgement.
The good news: After a third round of voting, smoke billowed from the chimney at 11:38 (10:38 GMT). The bad news: It was black. No Pope. Veteran Vatican watchers urge patience. For chimney-watchers on the square, the vigil goes on.
The cardinals will vote four times daily until a single candidate garners a two-thirds majority.
A successful vote would immediately be followed by white smoke and, soon afterwards, the Latin announcement "Habemus Papam" - we have a Pope.
Before the conclave began there was no clear frontrunner to replace Benedict XVI.
The 85-year-old stepped down last month, saying he was no longer strong enough to lead the Church, which is beset by problems ranging from a worldwide scandal over child sex abuse to allegations of corruption at the Vatican Bank.
SuspenseVoting takes place in silence, with no formal debate, until a decision is reached. If that does not happen after three days, there may be a pause for prayer and informal discussion for a maximum of one day.
Crowds waiting for a result once again braved rainy conditions in St Peters' Square to watch out for smoke issuing from the chimney.
After lunch, the cardinals will return to the Sistine Chapel to resume their deliberations.
The intense secrecy of the conclave process means we have no idea who has done well or badly in the early rounds of voting, the BBC's James Robbins in Rome says.
Conclave interactive video
Step inside our virtual Sistine Chapel as Philippa Thomas explains the process to elect a new Pope
But there could come a point after several days when the cardinals share a fear that indecision could be interpreted by the outside world as evidence of profound division, he adds.
In 2005 it took four votes for Cardinal Joseph Ratzinger - the future Benedict XVI - to be elected Pope.
But he was a clear favourite before the conclave began, and the long illness of his predecessor, John Paul II, meant cardinals had plenty of time to prepare and consider who they wanted to lead the church.
This time, speculation has focused on three contenders: Angelo Scola of Italy, Brazilian Odilo Scherer and Marc Ouellet of Canada.
But some analysts argue that Benedict's surprise abdication - the first by a Pope in six centuries - could be followed by an equally unusual outcome, with an outsider emerging as a compromise candidate.
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