Moscow has described further EU sanctions against prominent Russians over its annexation of Crimea from Ukraine as "detached from reality".
The foreign ministry said Russia reserved the right to an "appropriate response" after Brussels expanded its black list from 21 to 33 names.
Those on the list, who include close allies of President Vladimir Putin, face asset freezes and travel bans.
Meanwhile international observers are set to deploy in Ukraine.
Advance teams from the Organisation for Security and Co-operation in Europe (OSCE) are due to visit areas that include the troubled south-east after Russia dropped its objections.
However, the 100-strong OSCE Mission is not expected to go to Crimea.
Russia argues that Crimea has become part of Russia and therefore the mission has no mandate to go there.
In Crimea itself, forces allied to Russia have been seizing Ukrainian ships and taking over military bases.
The new authorities in Crimea have invited those serving in the Ukrainian forces on the peninsula to switch sides and join Russian forces.
'Regrettable' moveOn Friday, the EU announced sanctions against 12 Russians including Deputy Prime Minister Dmitry Rogozin, State Duma speaker Sergei Naryshkin, Kremlin political strategist Vladislav Surkov and Mr Putin's top adviser on Ukraine, Sergei Glazyev.
All four men are already under US sanctions for their involvement in the crisis over Crimea.
- 21 Nov 2013: President Viktor Yanukovych abandons an EU deal
- Dec: Pro-EU protesters occupy Kiev city hall and Independence Square
- 20-21 Feb 2014: At least 88 people killed in Kiev clashes
- 22 Feb: Mr Yanukovych flees; parliament removes him and calls election
- 27-28 Feb: Pro-Russian gunmen seize key buildings in Crimea. Parliament, under siege, appoints pro-Moscow Sergei Aksyonov a PM
- 6 Mar: Crimea's parliament votes to join Russia
- 16 Mar: Crimea voters choose to secede in disputed referendum
- 17 Mar: Crimean parliament declares independence and formally applies to join Russia
- 18 Mar: Russian and Crimean leaders sign deal in Moscow to join the region to Russia
The Russian foreign ministry said in a statement on Saturday that the European Council's decision to impose the sanctions was "regrettable" and "detached from reality".
It called for both sides to return to a "pragmatic basis for co-operation that meets our countries' interests" but warned that Russia reserved "the right to give an adequate response to the action taken".
President Putin signed a law formalising Crimea's annexation on Friday, despite the sanctions and international outcry over his actions in Ukraine.
The OSCE, which has 57 member-states in both Europe and North America, reached a deal on dispatching observers on Friday evening.
The Vienna-based group said that initially 100 civilian observers would deploy for six months in nine regions of Ukraine. Up to 400 extra personnel could be deployed if necessary.
The areas the monitors are due to visit include Odessa, Donetsk, Dnepropetrovsk, and Luhansk, which have been recently rocked by clashes between pro-Ukrainian and pro-Russian activists.
Washington tried to argue that the mission had a "mandate to work in Crimea and in all other parts of Ukraine".
On Saturday, the Russian foreign ministry said: "The mission's mandate reflects the new political and legal realities and does not apply to Crimea and Sevastopol, which became a part of Russia."
It said it hoped the mission would "help to overcome the internal Ukrainian crisis, stop rampant nationalist banditry and eradicate ultra-radical tendencies".
Earlier this month OSCE monitors had to abandon attempts to visit Crimea after warning shots were fired at the border with the Ukrainian mainland.
Are you in Crimea or the wider region? What are your thoughts on recent events? Email us at haveyoursay@bbc.co.uk with the subject heading 'Crimea'.
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